Synchrotron X-ray diffraction studies of LiMn2O4 and Li4Mn5O12 structures at high pressure
Experimental study of the phase transition in the lithium-excess lithium-manganese spinel over the pressure range 0-13 GPa has shown its suppression. This observation implies that the Li/Mn ratio, associated with the manganese oxidation state, plays an important role in the high-pressure phase transformation of the lithium-manganese spinels. As indicated by the results, the occupation of the octah