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Photoelectron spectroscopy study of free potassium clusters: Core-level lines and plasmon satellites

Free neutral potassium clusters of two different mean sizes were produced using a gas aggregation source. The K 3p core level was probed by means of synchrotron radiation based photoelectron spectroscopy. The absolute binding energy and the intensity ratio of the surface and bulk spectral features were used to obtain independent estimates of the cluster size. Plasmon satellites in core level spect

Molecular origin of time-dependent fluorescence shifts in proteins

Time-resolved fluorescence spectroscopy is used increasingly to probe molecular motions at the aqueous interfaces of biological macromolecules and membranes. By recording the time variation of the fluorescence frequency, thermal atomic fluctuations in the vicinity of the chromophore can be probed. From such fluorescence Stokes shift (FSS) experiments, it has been inferred that water motions in the

Influence of ferrocene addition to a laminar premixed propene flame: Laser diagnostics, mass spectrometry and numerical simulations

The detailed influence of ferrocene in a low-pressure, fuel-rich, laminar, premixed propene/oxygen/ argon flat flame was investigated experimentally using molecular beam sampling mass spectrometry (MBMS), laser-induced fluorescence (LIF), and compared to numerical simulations. MBMS was applied to analyze the species profiles of important intermediates in the flames with and without ferrocene dopin

Multiple interactions and the structure of beam remnants

Recent experimental data have established some of the basic features of multiple interactions in hadron-hadron collisions. The emphasis is therefore now shifting, to one of exploring more detailed aspects. Starting from a brief review of the current situation, a next-generation model is developed, wherein a detailed account is given of correlated flavour, colour, longitudinal and transverse moment

Electronic structure and chemical bonding in the ground states of Tc-2 and Re-2

Multiconfiguration second-order perturbation theory, including relativistic effects and spin-orbit coupling, has been employed to investigate the nature of the chemical bonding in the ground state of Tc-2 and Re-2. The Tc-2 ground state is found to be a 0(g)(+) state, with an effective bond order (EBO) of 4.4, and a dissociation energy of 3.25 eV. The Re-2 ground state is a 1(g) state, with EBO =

Camera Resectioning from a Box

In this paper we describe how we can do camera resectioning from a box with unknown dimensions, i.e. determine the camera model, assuming that image pixels are square. This assumption is equivalent to assuming that the camera as an aspect ratio of one and zero skew, and holds for most - if not all - digital cameras. Our proposed method works by first deriving 9 linear constraints on the projective

Antibodies against oxidized low-density lipoprotein for the treatment of vulnerable plaques

Inflammation caused by the accumulation of oxidized low-density lipoprotein (oxLDL) in the arterial wall is a key factor in the development of atherosclerosis. Accumulating evidence suggests that adaptive immune responses to oxLDL are of major importance in regulating the inflammatory response, and that humoral immunity largely has a protective effect in this process. This concept is supported by

Ligand specificity of the anaphylatoxin C5L2 receptor and its regulation on myeloid and epithelial cell lines

During complement activation the pro-inflammatory anaphylatoxins C3a and C5a are generated, which interact with the C3a receptor and C5a receptor (CD88), respectively. C5a and its degradation product C5a-des-Arg(74) also bind to the C5a receptor-like 2 (C5L2). C3a and C3a-des-Arg(77), also called acylation-stimulating protein, augment triglyceride synthesis and glucose uptake in adipocytes and ski

Patients' evaluation of pain and nurses' management of analgesics after surgery. The effect of a study day on the subject of pain for nurses working at the thorax surgery department

The effect of a study day on the subject of pain for nurses working at the thorax surgery department The aims of this investigation were: to describe patients' evaluation of pain and the treatment of pain after thorax surgery via sternotomy; to repeat the evaluation with another group of patients following a study day for nurses, featuring pain and pain treatment; and to examine whether the study

Competitive surface complexation of o-phthalate and phosphate on goethite (alpha-FeOOH) particles

Complexation of o-phthalate (1,2-benzenedicarboxylate) and competitive complexation of phosphate and phthalate at the goethite-water interface have been studied in 0.1 M Na(NO3) media at 298.2 K within the range 3.0 < -log [H+] < 8.5. Equilibrium measurements were performed as potentiometric titrations supplemented with spectrophotometric phosphate and phthalate analyses. The binary and ternary ch

Applying the Case Method for Teaching within the Health Professions - Teaching the Students.

Context: When using the Case Method in teaching situations, problem-solving is emphasized and taught, in order to acquire the skills and later be able to apply them in new situations. The basis of the learning process is the students’ own activity in the situation and is built on critical appraisal and discussion. Objectives: To explain what the Case Method is, what it is not and to describe when

Differential expression of chemokine receptors on human IgA plus and IgG plus B cells

Organ-specific lymphocyte homing is dependent on the expression of tissue-specific homing receptors and selected chemokine receptors. During the effector phase of an immune response, IgA and IgG antibody-secreting cells (ASC) are differently distributed in the body. Still, B cell expression of L-selectin and the mucosal homing receptor integrin alpha 4 beta 7 is not related to the isotype produced

Cramer-Rao lower bounds for inverse scattering problems of multilayer structures

In this paper, the inverse scattering problem of amultilayer structure is analysed with the Fisher information matrix and the Cramer-Rao lower bound (CRLB). The CRLB quantifies the ill-posedness of the inverse scattering problem in terms of resolution versus estimation accuracy based on the observation of noisy data. The limit for feasible inversion is identified by an asymptotic eigenvalue analys

Capillary filtration coefficient is independent of number of perfused capillaries in cat skeletal muscle

The capillary filtration coefficient (CFC) is assumed to reflect both microvascular hydraulic conductivity and the number of perfused capillaries at a given moment (precapillary sphincter activity). Estimation of hydraulic conductivity in vivo with the CFC method has therefore been performed under conditions of unchanged vascular tone and metabolic influence. There are studies, however, that did n