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Mechanistic investigation of platinum and palladium catalysed cross- coupling reactions. Implications for the Stille and Heck reactions.

Popular Abstract in Swedish Kol-kolinteraktioner utgör starka kemiska bindningar. Detta innebär att de är relativt svåra att både bryta och bilda. Föreliggande avhandling sammanfattar mekanistiska studier av två reaktioner, Stillereaktionen och Heckreaktionen, med hjälp av vilka kol-kolbindningar kan bildas. Ett vanligt förekommande sammanfattningsnamn för denna typ av reaktioner är korskopplingsrThe present thesis deals with various types of palladium(II) and platinum(II) complexes and their use in homogeneous catalysis. The focus has been devoted to mechanistic investigations concerning the Stille and Heck reactions and studies under both catalytic and stoichiometric conditions were conducted. As a stoichiometric probe for studying the transmetallation step in the Stille reaction the pl

Ecological and evolutionary assembly processes and metacommunity structure

Popular Abstract in Swedish Ett biologiskt samhälle definieras av de arter som lever och interagerar på en plats. Platsen kan vara en sjö, en ö eller ett skogsparti. Om det dessutom finns flera platser som arter sprider sig mellan brukar man tala om ett metasamhälle. Idag vet man att både ekologiska och evolutionära processer påverkar metasamhällens uppbyggnad, stabilitet och funktionalitet. DenThis thesis aims to elucidate the link between abiotic and biotic effects and biogeographical contingencies, eco-evolutionary assembly processes, and community structure in a spatially explicit metacommunity framework. To this end, we used structure analysis of naturally sampled and experimentally manipulated marine bacterial communities and mathematical eco-evolutionary modeling and simulations o

Vad kan vi lära oss efter fem år med CEQ?

LTH:s policy för kvalitetsarbete kring grund- utbildningen placerar studenternas lärande i fokus, och anger att den pedagogiska utvecklingen ska bygga på en väl- informerad dialogprocess. Enkäten CEQ används sedan hösten 2003 i stor omfattning som dataunderlag i kvalitetsarbetet. Under de första fem åren har stora mängder data samlats in, men inte särskilt många undersökningar gjorts på materialet

Colour holography in optics courses at Lund Institute of Technology

Several physics courses are given at Lund Institute of Technology. In the basic courses on ray and wave optics, holography has played an important role both in stimulating the students to curiously investigate the optical world and as an important visualisation of some obvious and interesting parts of the courses. To meet the need for basic laboratory experience, a holographic laboratory has been

Control of moisture safety design by comparison between calculations and measurements in passive house walls made of wood

The use of passive house technique has been used in a new wood framed building in Sweden. Besides the positive effect of reduced energy need, highly insulated wooden houses often have a higher risk of moisture and mould problems. The reason is that critical positions is more exposed to higher relative humidity compared to ordinary houses with thinner insulation. To investigate if an external wall

Post-Tsunami Recovery in Thailand: Socio-cultural responses

Of all the huge natural disasters that claimed the lives of thousands in Asia, the Indian Ocean tsunami in 2004 was the largest, estimated to have killed more than 230,000 people. The scope of damage brought about by this natural disaster urges focus on recovery and post-disaster reconstruction from several perspectives. Here we find an in-depth ethnography of Thailand and the role of culture and

Energy use, population and growth, 1800-1970

In this paper, the role of energy use is incorporated into unified growth theory. The paper presents some interesting evidence about the evolution of energy in the transition from stagnation to growth, and it subsequently develops a growth model where the observed increase in conversion efficiency in the coal energy sector is explicitly modelled and calibrated to existing data over the period 1800

A Control Theory Approach for Analyzing the Effects of Data Errors in Safety-Critical Control Systems

Computers are increasingly used for implementing controlalgorithms in safety-critical embedded applications, such asengine control, braking control and flight surfacecontrol. Addressing the consequent coupling of control performancewith computer related errors, this paper develops a composite computerdependability/control theory methodology for analyzing the effectsdata errors have on control syst