Photochemistry of diiodomethane in solution studied by femtosecond and nanosecond laser photolysis. Formation and dark reactions of the CH2I-I isomer photoproduct and its role in cyclopropanation of olefins
Femtosecond and nanosecond photolysis of CH2I2 in acetonitrile at an excitation wavelength of 266-nm yield the ground-state CH2I-I isomer product in similar to70% quantum yield. High isomer formation quantum yields (> 70%) were measured also in n-hexane, dichloromethane, methanol, and ethanol using nanosecond photolysis. The CH2I-I product is formed biphasically within similar to15 ps after excita