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Exploiting anisotropic particle shape to electrostatically assemble colloidal molecules with high yield and purity

Hypothesis: Colloidal molecules with anisotropic shapes and interactions are powerful model systems for deciphering the behavior of real molecules and building units for creating materials with designed properties. While many strategies for their assembly have been developed, they typically yield a broad distribution or are limited to a specific type. We hypothesize that the shape and relative siz

Microwave power harvesting using resonator-coupled double quantum dot photodiode

We demonstrate a microwave power-to-electrical energy conversion in a resonator-coupled double quantum dot. The system, operated as a photodiode, converts individual microwave photons to electrons tunneling through the double dot, resulting in an electrical current flowing against the applied voltage bias at input powers down to 1 fW. The device attains a maximum power harvesting efficiency of 2%,

Numerical insights on ionic microgels : Structure and swelling behaviour

Recent progress has been made in the numerical modelling of neutral microgel particles with a realistic, disordered structure. In this work we extend this approach to the case of co-polymerised microgels where a thermoresponsive polymer is mixed with acidic groups. We compare the cases where counterions directly interact with microgel charges or are modelled implicitly through a Debye-Hückel descr

Microgels Adsorbed at Liquid-Liquid Interfaces : A Joint Numerical and Experimental Study

Soft particles display highly versatile properties with respect to hard colloids and even more so at fluid-fluid interfaces. In particular, microgels, consisting of a cross-linked polymer network, are able to deform and flatten upon adsorption at the interface due to the balance between surface tension and internal elasticity. Despite the existence of experimental results, a detailed theoretical u

Walk It Like You Talk It: En Kvalitativ Studie om Etiska AI-Strategier

Research question: How are organizations integrating ethical and strategic considerations into their approaches to AI implementation? Purpose: The purpose of this research is to systematically map ethical and strategic themes relevant to Artificial Intelligence Systems within the business context from a practitioner standpoint. This study aims to contribute to the understanding of this research fi

Singular value decay of operator-valued differential Lyapunov and Riccati equations

We consider operator-valued differential Lyapunov and Riccati equations, where the operators B and C may be relatively unbounded with respect to A (in the standard notation). In this setting, we prove that the singular values of the solutions decay fast under certain conditions. In fact, the decay is exponential in the negative square root if A generates an analytic semigroup and the range of C ha

Numerical solution of the finite horizon stochastic linear quadratic control problem

The treatment of the stochastic linear quadratic optimal control problem with finite time horizon requires the solution of stochastic differential Riccati equations. We propose efficient numerical methods, which exploit the particular structure and can be applied for large-scale systems. They are based on numerical methods for ordinary differential equations such as Rosenbrock methods, backward di

Graphite oxide by “chlorate route” oxidation without HNO3 : Does acid matter?

Very strong difference in many properties is well documented for graphite oxides (GtO) synthesized by Brodie (BGO) and Hummers (HGO) methods. The difference is typically assigned to the type of oxidant (chlorates or KMnO4, respectively). However, not only oxidants but also acids used in these methods are different. It is still unclear which of the different properties of GtO are dependent on the o

Reclaiming the Past and the Present: The Presentation and Representation of Ethnic Minorities in Cultural Institutions

Cultural institutions such as museums and art galleries are important agents in educating the broader public on matters where current awareness is missing, inadequate or inaccurate. In this study, I focus on one such matter, which is the knowledge regarding ethnic minorities, their history, traditions, and current challenges. My primary focus is on how cultural institutions utilise their exhibitio

Digital PCR quantification of ultrahigh ERBB2 copy number identifies poor breast cancer survival after trastuzumab

HER2/ERBB2 evaluation is necessary for treatment decision-making in breast cancer (BC), however current methods have limitations and considerable variability exists. DNA copy number (CN) evaluation by droplet digital PCR (ddPCR) has complementary advantages for HER2/ERBB2 diagnostics. In this study, we developed a single-reaction multiplex ddPCR assay for determination of ERBB2 CN in reference to

The Genetics of Diabetes

The chronic hyperglycaemia of diabetes is associated with long-term damage, dysfunction, and failure of different organs, especially the eyes, kidneys, nerves, heart, and blood vessels. The increasing prevalence of type 2 diabetes can largely be ascribed to the worldwide increase in obesity during the last 30 years; for instance, more than 60% of individuals older than 15 years in the UK and USA a

Buckling and Interfacial Deformation of Fluorescent Poly(N-isopropylacrylamide) Microgel Capsules

Hollow microgels are fascinating model systems at the crossover between polymer vesicles, emulsions, and colloids as they deform, interpenetrate, and eventually shrink at higher volume fraction or when subjected to an external stress. Here, we introduce a system consisting of microgels with a micrometer-sized cavity enabling a straightforward characterization in situ using fluorescence microscopy

Association between dietary pesticide exposure profiles and body weight change in French adults : Results from the NutriNet-Santé cohort

BACKGROUND: Pesticides cause a wide range of deleterious health effects, including metabolic disorders. Little is known about the effects of dietary pesticide exposure on body weight (BW) change in the general population. We aimed to investigate the role of dietary pesticide exposure in BW change among NutriNet-Santé participants, focusing on potential sexual dimorphism.METHODS: Participants compl

Numerical Modeling of Chemical Kinetics, Spray Dynamics, and Turbulent Combustion towards Sustainable Aviation

With growing interest in sustainable civil supersonic and hypersonic aviation, there is a need to model the combustion of alternative, sustainable jet fuels. This work presents numerical simulations of several related phenomena, including laminar flames, ignition, and spray flames. Two conventional jet fuels, Jet A and JP-5, and two alternative jet fuels, C1 and C5, are targeted. The laminar burni

SYSTEMATIC POSITION AND CONSERVATION ASPECTS OF MELINAEA MNASIAS THERA (LEPIDOPTERA: NYMPHALIDAE: DANAINAE)

The tribe Ithomiini (Nymphalidae: Danainae) includes nearly 400 species of butterflies distributed from Mex-ico to Northern Argentina, and adults of all species are aposematic and the main models in several Neotropical mimicry rings. The subtribe Melinaeina, a small group composed of five genera of large ithomiines, is the sister group of all remaining groups in the tribe Ithomiini. With 14 recogn

The Historical Methodological Foundation of Phenomenography

Phenomenography is a research tradition originating from research on students’ studying and learning. The research methods of phenomenography have been discussed and criticized by many authors. There is a need for a presentation of the historical methodological foundation of phenomenography. The phenomenographic research methods are best understood as placed within the general research methodology

On cyclicity in de Branges-Rovnyak spaces

We study the problem of characterizing the cyclic vec-tors in de Branges-Rovnyak spaces. Based on a description of theinvariant subspaces we show that the difficulty lies entirely in un-derstanding the subspace (aH2)⊥ and give a complete function the-oretic description of the cyclic vectors in the case dim(aH2)⊥ < ∞.Incidentally, this implies analogous results for certain generalizedDirichlet spac

Spectrally resolved insect flashes by sunlight

Insects are vital for the environment and biodiversity. Optics-based remote techniques can quickly and effectively identify and track insects in their natural habitat. This has the potential to speed up and improve the time-consuming process of manually monitoring insect diversity. This thesis presents a method to remotely sense insects by analyzing the sunlight reflected by free-flying insects. T

Guiding the self-assembly of colloidal diamond

The assembly of colloidal cubic diamond is a challenging process since the shape and interaction parameters and the thermodynamic conditions where this structure is stable are elusive. The simultaneous use of shape-anisotropic particles and strong directional interactions has proven to be a successful path to exclusively nucleate this structure. Here, using molecular dynamics simulations, we explo