Cellulose–solvent interactions from self-diffusion NMR
Molecular self-diffusion coefficients were measured in solutions of microcrystalline cellulose (MCC) and dissolving pulp, in 40 wt% aqueous tetrabutylammonium hydroxide (TBAH), using pulsed field gradient stimulated echo NMR. From the cellulose diffusion coefficients, a weight averaged radius of hydration h>w = 6.1 nm for MCC and h>w = 15 nm for pulp were obtained. Water and TBA+ ions show a signi
