Simulation of transients in heterogeneous catalysis: a comparison of the step- and pulse-transient techniques for the study of hydrocarbon oxidation on metal oxide catalysts
The responses to step and pulse transients with reactants have been simulated for conventional step-transient conditions at atmospheric pressure and pulsing under vacuum using a temporal analysis of products (TAP) reactor, respectively. Propene oxidation over an oxide catalyst with the participation of lattice oxygen was chosen as a model reaction. The mechanism comprises adsorption of the reactan