Fe-N-heterocyclic carbene (NHC) complexes attract increasing attention as photosensitisers and photoredox catalysts. Such applications generally rely on sufficiently long excited state lifetimes and efficient bimolecular quenching, which leads to there being few examples of successful usage of Fe-NHC complexes to date. Here, we have employed [Fe(iii)(btz)3]3+ (btz = (3,3′-dimethyl-1,1′-bis(p-tolyl

For the longest of times, commerce and empire have been held to reside in perfect isolation from one another. Conceptually, peaceful commerce starkly opposed the discord of empires. In that same vein, political economy – the tool of commerce – was often considered the natural counterpart of warfare – the tool of empire. In many regards political economy was – and still is – considered an appealing

The high-pressure phase Na8BxSi46-x(3 < x < 5) is the first representative of a borosilicide crystallizing in the rarely occurring clathrate VIII type structure. Crystals with composition Na8B4Si42(space group I43¯ m; a = 9.7187(2) Å Pearson symbol cI54) were obtained at 5-8 GPa and 1200 K. The clathrate I modification exists for the same composition at lower pressure with a larger cell volume (Pm

The Swedish folklore collector Eva Wigström collaborated in the 1890s with the young artist and illustrator Gisela Trapp. They both lived in Helsingborg in the south of Sweden and shared many interests, despite a difference in age of about 40 years. In this article we are introduced to Wigström’s work as an author and folklore collector, and the cooperation between the two women is described. Wigs

Measurement and feedback control are essential features of quantum science, with applications ranging from quantum technology protocols to information-to-work conversion in quantum thermodynamics. Theoretical descriptions of feedback control are typically given in terms of stochastic equations requiring numerical solutions, or are limited to linear feedback protocols. Here we present a formalism f

Hydrogenated graphene (H-Gr) is an extensively studied system not only because of its capabilities as a simplified model system for hydrocarbon chemistry but also because hydrogenation is a compelling method for Gr functionalization. However, knowledge of how H-Gr interacts with molecules at higher pressures and ambient conditions is lacking. Here we present experimental and theoretical evidence t

BACKGROUND The enteric nervous system (ENS) is situated along the entire gastrointestinal tract and is divided into myenteric and submucosal plexuses in the small and large intestines. The ENS consists of neurons, glial cells, and nerves assembled into ganglia, surrounded by telocytes, interstitial cells of Cajal, and connective tissue. Owing to the complex spatial organization of several intercon

Background: Fear of falling (FoF) is very common in persons with late effects of polio (LEoP). An internationally recognized rating scale to assess FoF is the Falls Efficacy Scale-International (FES-I). Yet, there is limited knowledge about its measurement properties in persons with LEoP. Objective: To investigate the measurement properties of the FES-I (16-item version) and the short FES-I (7-ite

Ammonia (NH3) is regarded as a promising future carbon-free fuel but needs to overcome drawbacks including extremely low burning velocity in practical combustion apparatus. In this study, ozone (O3) additive is used to elucidate one of the mechanisms of potential flame enhancement method based on plasma-assisted combustion. The effects of ozone addition on the laminar burning velocity of premixed

Background: The mast cell-specific metalloprotease CPA3 has been given important roles in lung tissue homeostasis and disease pathogenesis. However, the dynamics and spatial distribution of mast cell CPA3 expression in lung diseases remain unknown. Methods: Using a histology-based approach for quantitative spatial decoding of mRNA and protein single cell, this study investigates the dynamics of CP

Three metabolite patterns have previously shown prospective inverse associations with the risk of aggressive prostate cancer within the European Prospective Investigation into Cancer and Nutrition (EPIC). Here, we investigated dietary and lifestyle correlates of these three prostate cancer-related metabolite patterns, which included: 64 phosphatidylcholines and three hydroxysphingomyelins (Pattern

The building industry has a major environmental impact in terms of global energy use, carbon emissions, resource use, and the production of waste. To reach ambitious international environmental goals, the building industry faces a need for large-scale change. Circular strategies for buildings include using building and materials longer through lifetime extension strategies, reuse, sharing, renovat

Introduction: Successful aging is a multidimensional construct covering behavioral, social, and psychological domains of well-being. We aimed to identify well-being profiles and their association with mobility-limitation free survival. Methods: A total of 1488 healthy individuals aged 60+ from the Swedish National study on Aging and Care in Kungsholmen (SNAC-K) were followed-up for 15 years. Mobil

Kort introduktion till Toni Rønnow-Rasmussens bok The Value Gap (OUP 2022)

The purpose of this study is to investigate how a regional knowledge base of information and communication technologies (ICTs) influences the emergence of artificial intelligence (AI) technologies in European regions. Relying on patent data and studying the knowledge production of AI technologies in 233 European regions in the period from 1994 to 2017, our study reveals three results. First, ICTs

The molecular mechanisms regulating key fate decisions of hematopoietic stem cells (HSCs) remain incompletely understood. Here, we targeted global shRNA libraries to primary human hematopoietic stem and progenitor cells (HSPCs) to screen for modifiers of self-renewal and differentiation, and identified metastasis-associated 1 (MTA1) as a negative regulator of human HSPC propagation in vitro. Knock

Quantified indicators are increasingly used for performance evaluations in the science sectors worldwide. However, relatively little information is available on the expanding use of research metrics in certain transition countries. Central Asia is a post-Soviet region where newly independent states achieved lower research performance relative to comparators in key indicators of productivity and in