Characterization by fluorescence energy transfer of the core of polyisoprene-poly(methyl methacrylate) diblock copolymer micelles
Fluorescence decay measurements of the rate of non-radiative direct energy transfer have been employed to characterize the core and the core-corona interface of polyisoprene-poly(methyl methacrylate) (PI-PMMA) diblock copolymer micelles in acetonitrile. These micelles consist of a core of the insoluble PI blocks and a corona of the soluble PMMA blocks. The block copolymers are labeled, at the bloc