Ultrafast carotenoid band shifts probe structure and dynamics in photosynthetic antenna complexes
We report observations of ultrafast carotenoid band shifts correlated with energy transfer dynamics between bacteriochlorophyll (BChl) molecules within the peripheral light-harvesting complex (LH2) from the photosynthetic bacterium Rhodobacter sphaeroides. Direct excitation of the bacteriochlorophyll Q(y) bands yielded distinct changes in the carotenoid S2 absorption from 430 to 530 nm. Transient
