Thermochemistry of metallic alkyls : Part 7. - The heat of formation of mercury diphenyl, and of mercury phenyl chloride
The heat of reaction of mercury diphenyl with hydrogen chloride in benzene solvent has been measured at 25°C. The heat of reaction of mercury diphenyl with mercuric chloride in methanol solvent has also been measured. From these heats of reaction, the heat of formation of mercury diphenyl has been derived: ΔHf° (Hgφ2, cryst.) = 65.4 ± 2 kcal/mole. Previous data on the heats of reaction of mercury