Aggregation-Induced Emission in a Polymeric Photovoltaic Donor Material
In this work, we report the aggregation-induced emission in a polymeric donor material poly(bis(2-butyloctyl)[2,2′:5′,2″-terthiophene]-4,4″-dicarboxylate-5,5′-diyl-vinylene) (PTVT-T), which exhibits a high device performance for the application of photovoltaics. Time-dependent density functional theory calculations and steady-state and time-resolved spectroscopy have been employed to reveal the un