Large Footprint Pyrene Chromophores Anchored to Planar and Colloidal Metal Oxide Thin Films
Sensitization and binding of a large footprint pyrene chromophore to planar (sapphire) and colloidal metal oxide films (TiO2 and ZrO2) is investigated. The model compound combines a 1-pyrenyl-ethynylenephenylene unit with a new adamantane-tripodal linker that binds to the surface. The linker design, combining a large footprint (2 nm2) of the tripodal linker with the meta position of the COOH ancho