The homolytic cleavage of the organometallic Co-C bond in vitamin B-12-dependent enzymes is accelerated by a factor of similar to 10(12) in the protein compared to that of the isolated cofactor in aqueous solution. To understand this much debated effect, we have studied the Co-C bond cleavage in the enzyme glutamate mutase with combined quantum and molecular mechanics methods. We show that the cal

The upper limit of flammability of hydrogen in air, oxygen, oxygen-helium, oxygen-neon, oxygen-argon and oxygen-carbon dioxide mixtures was measured at room temperature and pressures between 0.97 and 29 atm in two cylindrical bombs with volumes of 1.5 and 5.2 liters. The limit in ternary mixtures was determined in 20%, 40%, 60% and 80% helium, 20% neon and argon and 10% carbon dioxide concentratio

Background Sensory information from mechanoreceptors in the skin, muscles, tendons, and joint structures plays an important role in joint stability. A joint injury can lead to disruption of the sensory system, which can be measured by proprioceptive acuity. When evaluating proprioception, assessment tools need to be reliable. The aim of this study was to assess the test-retest reliability of a de

Two-hundred ninety five patients with the antiphospholipid syndrome (APS) were studied for the presence of antibodies against six anti-beta2GPI-related peptides Abs. The prevalence of a wide spectrum of clinical and laboratory parameters of APS was evaluated in all patients, and correlated with the presence of each anti-beta2GPI peptide antibody. The rates of the various antipeptides Abs ranged fr

Filmrecension av Robert Altmans Gosford Park

DNA chemical and physical networks have been investigated with respect to their stability and swelling, and rheological properties. Chemical networks were prepared by cross-linking DNA with ethylene glycol diglycidyl ether (EGDE), and physical networks by association with cationic polymers. Both types of gels display strong elastic properties and have a shear thinning behaviour. Addition of cation

Popular Abstract in Swedish De arida och semi-arida grässtäpperna i Norra Kina anses vara svårt drabbade av markförstöring, främst genom vind- och vattenerosion, men även genom försaltning. Den rådande uppfattningen är att markförstöring och ökenspridningsproblematiken har eskalerat sedan införandet av de ekonomiska reformerna efter 1978, bl.a. genom en expansion av den odlade arealen på tidigare This study challenges the prevailing assumption that the expansion of cultivated land areas and increasing number of livestock in the agro-pastoral regions of northern China have aggravated the process of land degradation since the start of the rural reforms in 1978. Land-use and productivity trends in the Inner Mongolia Autonomous Region (IMAR), with special attention to the Keerqin steppe region

Objective To study, in a large cohort, the association between the use of anti-asthmatic drugs during pregnancy and pregnancy complications. Methods Using the Swedish Medical Birth Register, we identified 24,369 women who reported the use of anti-asthmatic drugs in early pregnancy and 7778 women who were prescribed such drugs later during pregnancy by antenatal care system centres, during the peri

Gel swelling experiments have been used to study the binding of ionic surfactants to a series of nonionic alkylacrylamide hydrogels of increasing hydrophobicity. The binding of hexadecyl trimethylammonium (C-16-TA(+)) to uncharged gels is sensitive to both the hydrophobicity of the gel and the counterion to the surfactant. There is a minimum hydrophobicity threshold below which binding of the surf

High-spin states of T-z = 1 nuclei were studied with the reactions Ni-58(Si-28,3 alpha)Kr-74,Ni-58(Si-28,2 alpha)Sr-78, and Ni-58(Si-28,2p2n)Zr-82 at 130 MeV beam energy. The Gammasphere array in conjunction with the 4 pi charged-particle detector array Microball was used to detect gamma rays in coincidence with evaporated light charged particles. The known pi = +, alpha = 0 yrast bands were exten

Recension av Stéphane Bruchfeld & Paul A. Levine; ...om detta må ni berätta... En bok om Förintelsen i Europa 1933–1945.

Spray drying is a widely used process to produce pharmaceutical powders. In traditional spray drying, the particle size distribution is wide and not well controlled. Using EHD atomization for spray drying offers a possibility to tailor the particle size and morphology. In conventional EHD spray drying, the generated particles are charged and need to be discharged to avoid Rayleigh breakup. Dischar